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Macron, playing alongside a mix of former international players and healthcare professionals, fired his shot low into the bottom corner as the goalkeeper remained rooted to the line.
Everton's first derby victory at Goodison Park in more than 13 years prevented Liverpool from climbing level with Arsenal at the top of the league table. Juergen Klopp's men are three points behind the Gunners (77) with four games to play.
It was the sixth time Arsenal have scored five or more in a Premier League game this season without conceding and in such a tight race they now have a huge goal difference advantage which could prove crucial to the outcome.
Arsenal lead on 74 points, one point ahead of Manchester City.
City's Bernardo Silva and Mateo Kovacic both misfired in the shootout to put Madrid in the driving seat.
Arsenal's defeat, their first in 12 league games, sees them remain second, two points behind City and level on points with third-placed Liverpool with six games left to play.
Pep Guardiola's men have 73 points with six games remaining in a rip-roaring three-way title race, two points ahead of both Arsenal and Liverpool, who can climb over City with victories in their respective games on Sunday.
Federico Valverde salvaged a draw for Real late on after City had taken a 3-2 lead with sumptuous strikes from Phil Foden and Josko Gvardiol following a Ruben Dias own goal and Rodrygo strike that gave the hosts a half-time lead in Spain's capital.
Islamic State was alleged to have threatened four venues for this week's Champions League matches, including the Parc des Princes in Paris and two games in Madrid hosted by Real Madrid and Atletico Madrid.
With seven games remaining in the neck-and-neck title race, Liverpool and Arsenal have 71 points with the Gunners leading on goal difference. Holders Manchester City are third on 70 points, while United are sixth.