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The highly-rated fullback has signed a six-year contract with the Premier League heavyweights.
The win took Barca back up to third place on 68 points, five behind leaders Atletico Madrid but with a game in hand.
A Luis Suarez header gave Atletico Madrid a 1-0 home win over Getafe in coach Diego Simeone's 500th game in charge.
Barcelona fell to their first defeat in La Liga under new coach Ronald Koeman as they lost 1-0 at Getafe, hours after champions Real Madrid slipped to a 1-0 defeat at home to promoted Cadiz.
United booked a quarterfinal spot after their second-string side laboured to a 2-1 home win over LASK Linz to seal a 7-1 aggregate rout of the Austrian side.
The Champions League will resume in August after being halted in March due to the COVID-19 pandemic with a Final Eight tournament being held in Lisbon after the remaining second-leg games from the last 16 ties are decided.
The hard-fought win took Zinedine Zidane's side on to 77 points after 34 games, seven clear of second-placed Barca.
The report added that Messi is angry about leaked media reports that appeared to make him seem responsible for events at the club, such as the January sacking of coach Ernesto Valverde, and that he is frustrated about the squad's lack of quality.
Real, who have not won the title since 2017, lead the table on 74 points, four ahead of Barca with five games left and have a superior head-to-head record over the Catalans.
The draw meant the Catalans stayed second in the standings on 70 points and leaders Real Madrid, who have 71, will go four points clear at the top with five games left if they beat Getafe at home on Thursday.