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The captains from England, Wales, Belgium, the Netherlands, Switzerland, Germany and Denmark were planning on wearing the armbands to protest Qatar's laws against same-sex relationships.
De Boer has resigned two days after his side were beaten 2-0 by the Czech Republic and eliminated in the last 16 of the European Championship.
Emmen played their opening game of the new season without a logo on their shirt on Sunday as they were still looking for a sponsor. After agreeing a deal with EasyToys, they sought permission from the KNVB but it was swiftly denied.
Koeman, who has left his role as manager of the Netherlands, has signed a two-year-deal with Barcelona.
The 57-year-old has made no secret of the fact Barcelona would be a dream job and Dutch media said Koeman felt it was now or never to accept an offer from the Catalan giants.