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Yastremska, the world No. 93 who reached the third round at Melbourne Park in 2019, secured the early break in the second set as her opponent continued to spray the errors and the 23-year-old held firm to seal the victory.
Ukraine can still book a spot at a fourth consecutive European Championship via the playoffs in March.
Manchester United tasted a 1-3 defeat at Old Trafford while City won by the same margin against the Hammers.
Angel Di Maria took over as captain in Messi's absence and shone, providing two assists before halftime
His debut match in charge will be Italy's 2024 European Championship qualifier in North Macedonia on September 9.
Saudi Professional League (SPL) club Al-Hilal announced that Neymar had signed a deal until 2025.
There was no immediate comment from the Ligue 1 champions, owned by Qatar Sports Investments, but French newspaper L'Equipe said the deal could net 31-year-old Neymar 160 million euros ($175 million).
He guided Italy to success at the European Championship in 2021 but the team once again failed to qualify for last year's World Cup in Qatar.
Spain capitalised on a defensive lapse to take the lead inside three minutes as Yeremy Pino produced a cool finish
Over the years, Aishwarya has graced the festival with memorable looks, including a gold mermaid gown by Roberto Cavalli accompanied by coral lips and immaculate hair.