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NIA will take the accused to Kozhikode's Elathur and Kannur for further evidence collection on Sunday.
The deceased were employees of a fuel refilling station at Al-Khalidiyyah.
Thiruvananthapuram PTP Nagar Ward Councilor VG Girikumar was arrested.
The Army said operations are underway to catch the perpetrators.
According to preliminary invistigation, a gas cylinder leak led to the fire.
UAPA charges have also been levied on the accused.
The fire broke out on the fourth floor of the five-storey building around 12.35pm on Saturday.
The cops have received a CCTV image that shows Saifi wearing a different dress when he reached the Kannur railway station while fleeing.
Shahrukh Saifi, the lone accused in the case so far, had booked a ticket to Kozhikode from New Delhi. He, however, de-boarded the train at Shoranur, which the cops infer as a deliberate attempt to mislead the investigators in case of a probe.
According to the police, Shahrukh Saifi spent 15-and-half hours in Shornoor.
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