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The Argentine forward, who joined PSG on a two-year contract after leaving Barcelona, found the top corner superbly in the second half to add to Idrissa Gueye's early first-half opener and put the capital club top of Group A on four points.
Ronaldo is set to make $125 million before taxes in the 2021-22 season.
Nkunku became only the fourth player to score a Champions League treble and end up on the losing side.
Everton Ribeiro got his second goal in two games to help Brazil on their way to a 2-0 win over Peru in another World Cup qualifier.
Kuwait-based Shahzad Mohammed Rafi, 17, is one of the seven freestyle footballers selected to the '2021 Red Bull Neymar Jr's Five World Final' via Instagram entries from the world over.
All 20,545 tickets available were sold at the Auguste Delaune stadium to see 34-year-old Messi play and the fans, who chanted the Argentina forward's name, were rewarded in the 66th minute when he replaced the disappointing Neymar.
The Brazilian, the only player to claim three World Cup winner’s medals and a man often called the greatest footballer of all time, said all monies raised will help Brazil's fight against and recovery from the COVID-19 pandemic.
Not yet fully fit, Messi, along with Neymar and fellow new recruits Gianluigi Donnarumma and Sergio Ramos, did not make the match squad.
Messi will wear the number 30 shirt, the club confirmed in a video posted on its Twitter feed, headlined "a new diamond in Paris".
A move to PSG would reunite Messi, who has officially been a free agent since July 1, with his former Barcelona teammate Neymar.