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The young wrestler pulled out of the 86 kg title clsh against Iranian great Hazsan Yazdani due to an ankle injury sustained during the semifinal bout.
The Catalans started without all-time top scorer Lionel Messi as well as teenage sensation Ansu Fati and fell behind in the second minute.
Competing in his maiden senior world championship, Deepak moved to the final with a commanding 8-2 win over Switzerland's Stefan Reichmuth.
After the champions were surprisingly beaten 1-0 by Athletic Bilbao in their opening match of the season last week, they rebounded in style on Sunday.
The Paraguayan referee showed Medel a red card and even though Messi did not react, he too was sent off, prompting boos in Sao Paulos Corinthians arena.
Reigning champions Chile will face either Uruguay or Peru in Wednesday's semifinal in Porto Alegre.
Chile forward Alexis Sanchez continued his resurgent form at the Copa America by scoring the winning goal in his side's 2-1 victory over Ecuador.
The 23rd minute sending off put Uruguay firmly in the driving seat and Edinson Cavani with an acrobatic volley and Luis Suarez with a poachers goal made it 3-0 by half-time.
The Selecao's golden boy is dominating the build-up to a tournament he will miss due to an ankle injury for all the wrong reasons.
Lionel Messi fittingly sealed Barcelona's 26th La Liga title by coming off the bench to score the goal in a 1-0 win over Levante in front of a jubilant Nou Camp crowd.