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Timo Werner's 58th-minute penalty after a foul by Ben Davies on Konrad Laimer was enough for Julian Nagelsmann's Bundesliga high-flyers to take a narrow lead into the second leg on March 10, although they might rue not putting the last-16 tie to bed.
Borussia Dortmund's lethal teenage striker Erling Haaland scored twice in eight minutes.
Bayern Munich sealed consecutive victories over Tottenham with a 3-1 success at the Allianz Arena, while Real Madrid, Paris Saint-Germain and Juventus also finished their group campaigns on winning notes.
Pochettino has enjoyed unforgettable European nights as Tottenham manager but this will go down as one of his lowest moments since he took charge in 2014.
Every stadium will have some specialities and some emotional bonding with the fans.
Coutinho will wear the number 10 shirt previously worn by Dutchman Arjen Robben, who retired at the end of last season.
A 2018 World Cup finalist, Perisic, who also donned the colours of Borussia Dortmund and VfL Wolfsburg in the Bundesliga between 2011 and 2015, will play for Bayern starting Friday.
Robben won 12 league titles in a glittering career, and 96 caps for his country including playing in the 2010 World Cup final in Johannesburg.
The ECA is working with European soccer governing body UEFA on a proposal to redesign the Champions League and replace it with a competition featuring promotion and relegation that could be largely closed off to outsiders.
The 21-year-old Jovic, who joined Eintracht initially on loan in 2017 from Benfica, scored 17 goals in 32 Bundesliga matches last season.