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Villa, back in the top flight after a three-year absence, made sure of the win in stoppage time.
United did not manage a shot on target until the 86th minute as they fell to their sixth loss in eight games,
City, who beat Bournemouth 1-0 on Saturday, have 71 points while Liverpool have 70 after their fourth draw in their last six games.
Manchester City stumbled to the Premier League's shock defeat of the season so far with a sensational 3-2 reverse against Crystal Palace.
William Clyde Allen III, told investigators he wanted the letters to 'send a message,' though he did not elaborate.
Bournemouth and Everton maintained their unbeaten starts to the season in a dramatic match in which both sides ended with 10 men.
Chopra's throw of 85.17m put him way ahead of the field, including Moldova's Andrian Mardare (81.48m) and Lithuania's Edis Matusevicius (79.31m), who finished second and third respectively.