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Benzema, who has scored 29 goals in all competitions for Real this season, has not played for Les Bleus since 2015 after a blackmailing scandal over which he faces a trial in October.
United's defeat means City are 10 points clear with both sides having three games left to play.
With Chelsea looking secure in the top four, the final Champions League place looks to be a three-way fight between Leicester, West Ham United and Liverpool.
The news comes the morning after the London club said it was one of 12 clubs forming a breakaway European Super League.
Manchester City's first win at Anfield since 2003 left them top of the Premier League by five points and effectively knocked Liverpool out of the title race on Sunday.
Oliver Giroud's first-half header was cancelled out shortly after the break by Anwar El Ghazi as Villa held Chelsea 1-1.
Tottenham Hotspu conceded a late goal in a 1-1 draw away to Wolverhampton Wanderers.
Manchester United were held to a 2-2 draw at Leicester City while Manchester City climbed to fifth thanks to a 2-0 win over Newcastle United.
Manchester City got back to winning ways with a 1-0 victory at in-form Southampton while Newcastle United were held to a 1-1 draw at home to struggling Fulham.
Arsenal lost 1-0 at home to Burnley -- a fourth successive home league defeat for the first time since 1959 leaving the Gunners languishing down in 15th spot.