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Diogo Dalot was sent off in stoppage time for two yellow cards -- both for dissent.
Nearly 200 countries agreed at the summit to begin reducing global consumption of fossil fuel and adopt a raft of measures, including more clean energy production.
supporters of language to phase out fossil fuels and had the backing of major oil and gas producers such as the United States, Canada and Norway, as well as the European Union and scores of other governments.
A draft of a final deal, published on Monday by the United Arab Emirates, which holds the presidency of the summit, suggested eight options countries 'could' take to cut emissions.
While renewables are already expanding fast, the latest goal would require solar and wind power deployments to speed up a lot.
The draft has set the stage for contentious last-minute negotiations in the two-week summit in Dubai, which has laid bare deep international divisions over whether oil, gas and coal should have a place in a climate-friendly future.
Observers in the negotiations said Saudi Arabia and Russia were insisting that COP28 focus only on reducing climate pollution - with no mention of the fossil fuels causing it.
Azerbaijan confirmed late on Thursday it had struck a deal with Armenia that allows Baku to bid to host the COP29 talks without the threat of an Armenian veto.
Still unresolved is how the nearly 200 countries at COP28 will handle the issue of fossil fuels, the main source of climate-warming emissions.
The global mean temperature for the first 11 months of the year hit the highest level on record, 1.46°C (34.63°F) above the 1850-1900 average.