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Brighton had taken the game to Chelsea in the first half but fell behind after a defensive blunder in the 23rd minute when goalkeeper Mat Ryan fouled Werner in the area and Jorginho coolly converted the penalty.
Lautaro Martinez played chief tormentor as Inter Milan claimed an emphatic 5-0 victory against Shakhtar Donetsk to reach the Europa League final.
Defeat left Chelsea with 63 points, needing one more from their final game against Wolverhampton Wanderers to guarantee a place in next season’s Champions League after slipping to fourth as Manchester United drew 1-1 with West Ham United.
Chelsea, who face rivals Arsenal in the August 1 (Saturday) showpiece, had lost to United three times this season but dominated the match and took control with goals either side of half-time from Olivier Giroud and Mason Mount.
The draw meant the Catalans stayed second in the standings on 70 points and leaders Real Madrid, who have 71, will go four points clear at the top with five games left if they beat Getafe at home on Thursday.
Barca edged out Athletic Bilbao 1-0 as substitute Rakitic scored the winner off an assist by Messi.
While some users of the apps are meeting in person, many are romancing online because of the public health risks, often using in-app video chats.
The game was played without fans in line with the guidance of the Austrian government -- one of four matches held behind closed doors on Thursday.
After falling 2-0 down on the night, substitute Marcos Llorente struck twice in extra time and Alvaro Morata added a late third to ensure a famous victory for Diego Simeone's side.
The hosts went down to 10 men in the second half, before being reduced to nine players minutes before the full-time whistle. However, they showed great resilience to hold on.