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The 60-year-old did not win any trophies with Inter although he led his side into the Champions League with fourth-placed finishes in both his seasons in charge.
Visitors Chelsea desperately needed a response after back-to-back humiliating away losses, with last Sunday's 6-0 thrashing by Manchester City following a 4-0 reverse at Bournemouth.
Mario Mandzukic scored the only goal as Juventus killed off Inter Milan's challenge to move 11 points clear in Serie A.
Tottenham had one point from their opening three Group B games but with one match remaining they have seven and have leapfrogged Inter into second place by virtue of their head-to-head record against the Nerazzurri.
Barca were famously beaten 3-1 by Jose Mourinhos Inter in 2010 and had not won on any of their previous six visits to Italy.
Barca top Group B with nine points while Inter are second on six, with PSV Eindhoven and Tottenham Hotspur locked on a point each.
The French were one of the favourites going into Russia 2018 and they lived up to the billing by regaining the World Cup.