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Argentina's win, their first after a loss to Colombia and a draw with Paraguay, leaves them in second place in Group B on four points behind group winners Colombia, who beat Paraguay 1-0.
Argentina are still bottom of Group B with one point from two games but they could progress to the last eight with a win over third-placed Qatar in their final group game on Sunday.
The 23rd minute sending off put Uruguay firmly in the driving seat and Edinson Cavani with an acrobatic volley and Luis Suarez with a poachers goal made it 3-0 by half-time.
Portuguese coach Carlos Queiroz, who only took over Colombia after leaving his job with Iran at the end of the January-February Asian Cup, paid tribute to the side's collective effort.
Messi wasted the best chance of the game before Martinez's piledriver broke the deadlock when he skewed a rebound wide from close range, and the Barcelona forward also went on a thrilling solo run into the area but could not get a shot away.
Aguero, who scored 21 Premier League goals in 33 appearances for Manchester City this season, has been in international exile since after last year's World Cup in Russia.
The new feature allows users to select up to nine Facebook friends who they want to express their interest in.
The four national presidents committed to creating a local organising committee with a representative from each country to coordinate with CONMEBOL, South American football's governing body.
Paraguay condemned the horrific terror attack in Pulwama.
India's Tourism Minister Alphons Kannanthanam is accompanying Naidu on the tour.