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The world record holder and Olympic champion - unbeaten in more than two years - only sneaked into the final round of eight jumpers in last place before summoning a magical 15.08 metres on her final attempt.
After an opening half-hour in which the home side dominated possession, Alvarez broke the deadlock in the 31st minute.
It was a exciting match played in scorching heat and humidity at the Georgios Karaiskakis Stadium as an obstinate Sevilla caused many problems for a City defence which was often exposed
Haaland, who bagged a Premier League season-record 36 goals and a total of 52 in all competitions for treble winners City last season, slotted his side in front after four minutes.
Arsenal won 4-1 in shootout after the match ended 1-1 in regulation time.
Gvardiol is Pep Guardiola's second signing in this transfer window after Croatia midfielder Mateo Kovacic joined from Chelsea.
The Premier League heavyweights will visit India between September 21 and 27.
The 32-year-old has a contract until June 2025 with an option for a further year, while the Spanish champions also said they had included a buyout clause of 400 million euros ($435.72 million).
Gundogan will leave City after captaining the English club to the Premier League, FA Cup and Champions League last season, ending a successful seven-year stint in England where he won 14 trophies, including five league titles.
City were crowned European champions for the first time and they also secured the treble of Premier League, FA Cup and Champions League, with Guardiola becoming the first men's manager in history to achieve the feat on more than one occasion.