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Officials said at least one person died in the shelling and a second person was killed by falling debris after a missile strike on another part of the Ukrainian capital.
Ukrainian President Volodymyr Zelenskyy said Russia was sending in new troops after Ukrainian forces had put 31 of its battalion tactical groups out of action.
Russia warned it could stop the flow of gas through pipelines from Russia to Germany in response to Berlin's decision last month to halt the opening of the controversial new Nord Stream 2 pipeline.
Moscow had earlier said it would let residents of Ukraine's two main cities flee in corridors to Russia and Belarus.
Some cybersecurity experts have expressed concern that soliciting help from freelancers could have dangerous escalatory consequences.
Russia faced deepening isolation and economic turmoil as Western nations, united in condemnation of its assault, hit it with an array of sanctions.
Russian forces pounded several cities with missiles overnight, setting an oil terminal ablaze in the town of Vasylkiv, southwest of the capital, Kyiv, its mayor said.
On Thursday, Russia invaded Ukraine. Russian President Vladimir Putin stated that the 'aim of the special military operation was to protect Russia and demilitarise Ukraine'.
Chief Minister Pinarayi Vijayan in a letter to the Union Foreign Minister S Jaishankar had said that there were 2,320 Malayali students in Ukraine.
Gunfire rattled near the capital's main airport, the Interfax news agency said, and sirens were heard over the city.