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There was no immediate comment from the Ligue 1 champions, owned by Qatar Sports Investments, but French newspaper L'Equipe said the deal could net 31-year-old Neymar 160 million euros ($175 million).
PSG opened their Ligue 1 title defence with a goalless draw at home against Lorient on Saturday as the team's prize asset watched from the stands.
Rani had on Thursday lashed out at the national head coach Janneke Schopman demanding an answer as to why she was being ignored despite her fair performances lately.
Bayern did not disclose the transfer fee, which media reports have put at around 100 million euros ($109 million). That would be a Bundesliga record.
The sixth-ranked La Roja had not advanced past the round of 16 in two previous two World Cup appearances.
A trademark curling free-kick in the 85th minute, Messi's seventh goal in four games for Miami, took the game to a shootout after the Argentine's side had trailed 4-2 with 10 minutes to go.
Alves has been jailed on remand for over six months for alleged sexual assault of a woman in a Barcelona nightclub last December.
The 24-year-old French captain, who still has one year remaining on his contract, is unwilling to renew his contract with PSG.
A packed stadium greeted the seven-time Ballon d'Or winner during his unveiling in Florida.
Get ready to binge-watch a captivating lineup of new releases this weekend, including 'Ntikkakkakkoru Premandaarnnu', 'Kohrra', and 'The Trial'.