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Cavani had been sent off in Uruguay's 1-0 defeat to Chile in the 2015 Copa America quarter-finals after being provoked by Gonzalo Jara and he and his team mates celebrated the goal as if it had just won them a trophy.
Uruguay lead Group C with four points, while Japan are third with one.
The 23rd minute sending off put Uruguay firmly in the driving seat and Edinson Cavani with an acrobatic volley and Luis Suarez with a poachers goal made it 3-0 by half-time.
Despite the recent slump, PSG secured the Ligue 1 title last month and remain 17 points clear at the top of the table, while Nice are seventh on 52 points.
The runaway champions can clinch a domestic double when they take on Stade Rennais in the French Cup final next Saturday.
United had never previously lost at home in European competition by a margin of more than one goal and history suggests their task in the second leg is extremely tough.
Paris St Germain's German coach Thomas Tuchel was pleased with how his side handled the pressure in the cauldron of Red Star's ground.
The result sees PSG leapfrog last year's finalists Liverpool, with eight points to Liverpool's six, with Napoli top of the group on nine and everything still to play for in the final round of matches.
The visitors were heading for top spot until Di Maria's goal threw the group wide open and provided a fitting end to an enthralling match.
Ronaldo's nomination comes after the 33-year-old last week denied rape allegations levelled against him by a woman who sued him in court in the United States.