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Mbappe, who turned down Real and signed a new three-year deal at PSG last month, topped the list with an estimated transfer value of 205.6 million euros ($219.5 million), beating Vinicius (185.3 million euros) and Haaland (152.6 million euros).
The defending champions went ahead through Adrien Rabiot's goal early in the second half but Andrej Kramaric's late penalty gave the hosts a deserved draw.
Denmark came from behind to defeat France 2-1 in their Group A1 clash at the Stade de France.
Mbappe was widely tipped for a move to the Spanish capital but signed a contract extension until 2025 at PSG last week in a dramatic U-turn, a decision that irked many Real players and fans.
Mbappe had been widely tipped to join Real Madrid this summer but stunned the Spanish champions by signing a contract extension until 2025 with PSG last week.
Manchester City sailed through to the quarterfinals after they played out a 0-0 draw against Sporting in their last-16 second leg, progressing 5-0 on aggregate.
PSG missed several chances and were thwarted by Real keeper Thibaut Courtois, who denied Mbappe on several occasions before superbly pushing away Messi's spot kick in the second half.
Holders Chelsea will face French champions Lille, just as they were drawn in the original draw, while six-times champions Bayern Munich will now face RB Salzburg.
PSG also advanced to the last 16 thanks to Leipzig's win over Club Brugge but the loss highlighted their continued problems in finding an effective way to harness their star-studded attack.
Holders France ran riot to reach the finals with a match to spare after four goals from Kylian Mbappe helped them to an 8-0 home demolition of Kazakhstan.