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Holders France ran riot to reach the finals with a match to spare after four goals from Kylian Mbappe helped them to an 8-0 home demolition of Kazakhstan.
The Dutchman, who had struggled this season after joining from Liverpool, struck in the 21st minute and headed in another goal six minutes before halftime.
It was the 34th time that Messi scored at least two goals in a Champions League game, bringing the Argentina captain's total to 123 goals in the tournament.
Goals from Karim Benzema and Kylian Mbappe earned them a 2-1 win over Spain at the San Siro.
A last-minute strike from Theo Hernandez secured the world champions a place in Sunday's final.
The Argentine forward, who joined PSG on a two-year contract after leaving Barcelona, found the top corner superbly in the second half to add to Idrissa Gueye's early first-half opener and put the capital club top of Group A on four points.
Ronaldo is set to make $125 million before taxes in the 2021-22 season.
Nkunku became only the fourth player to score a Champions League treble and end up on the losing side.
France's winless streak stretched to five games.
All 20,545 tickets available were sold at the Auguste Delaune stadium to see 34-year-old Messi play and the fans, who chanted the Argentina forward's name, were rewarded in the 66th minute when he replaced the disappointing Neymar.