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Eighth seed Ruud held his nerve as five unforced errors from Djokovic allowed him to go 3-0 up in the decider and he calmly closed out the victory.
Nagal threatened to spoil Rune's party by taking the second set after the second round match, which was suspended due to rain on Wednesday, resumed. However, he lost his serve twice in the final set.
PSG came into the match unbeaten in their last 27 games in all competitions but were undone by a fired-up Barcelona side looking to return the club to the summit of European football.
Federico Valverde salvaged a draw for Real late on after City had taken a 3-2 lead with sumptuous strikes from Phil Foden and Josko Gvardiol following a Ruben Dias own goal and Rodrygo strike that gave the hosts a half-time lead in Spain's capital.
Islamic State was alleged to have threatened four venues for this week's Champions League matches, including the Parc des Princes in Paris and two games in Madrid hosted by Real Madrid and Atletico Madrid.
Nagal became the first Indian player to win a singles main draw match at an ATP Masters event on clay.
Bilbao are the fourth oldest Spanish club and among three never to be relegated, alongside Real Madrid and Barcelona.
Rubiales was returning to Spain amid a judicial probe into the business deal to hold the Spanish Super Cup in Saudi Arabia.
Sinner won 88 per cent of his first serve points and thumped 15 winners to capture the title in South Florida after finishing as the runner-up in 2021 and 2023.
Bopanna and Ebden rallied to down Ivan Dodig and Austin Krajicek 6-7(3), 6-3, 10-6 in a hard-fought final.