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The top billing for the men's and women's categories are J Vishnu Vardhan from Telangana and Pooja Ingale from Maharashtra.
Novak Djokovic to play US wildcard Nishesh Basavareddy as the main round starts on Sunday.
Born in Manacor on the Mallorca island of Spain in June 1986, Nadal was a natural athlete who took a fancy to football more than tennis in his early years.
The Mallorcan, who played on four Davis Cup-winning teams for Spain, was tearful as the national anthem was played before the tie.
The 38-year-old Spaniard has won 22 Grand Slam titles.
From next season, seven of the nine ATP Masters 1000 events will be held across 12 days.
Bolelli and Vavassori, the fourth seeds, dominated from the outset.
Sinner, Zverev, four-time Grand Slam winner Carlos Alcaraz, former US Open champion Daniil Medvedev and American Taylor Fritz have booked their spots at the ATP Finals.
The third seed, Zverev produced 15 winners and nine unforced errors, compared to 12 and 25, respectively, for Humbert.
The season-ending tournament will be held at Turin from November 10-17.
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