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Pune's interim coach Pradhyum Reddy has made four changes to his side that lost to Bengaluru FC.
Valencia came out with renewed energy and spirit in the second half and took the game to Madrid but failed to keep their cool whenever they managed to find an opening.
Tottenham had one point from their opening three Group B games but with one match remaining they have seven and have leapfrogged Inter into second place by virtue of their head-to-head record against the Nerazzurri.
Real's win thanks to second-half goals from Gareth Bale and Lucas Vazquez means the European champions are guaranteed to top the group due to a better head-to-head over the hosts.
Barca's Philippe Coutinho opened the scoring in the 11th minute following a slick team move.
Real Madrid are on a run of three defeats and a draw in their last four league games which has left the side sitting in seventh place.
Real Madrid snapped a run of five games without victory by earning a 2-1 win at home to Viktoria Plzen in the Champions League.
Real set an unwanted record of 482 minutes without scoring a goal in the process.
Ronaldo's nomination comes after the 33-year-old last week denied rape allegations levelled against him by a woman who sued him in court in the United States.
Real Madrid mounted wave upon wave of attacks, and wasted several chances in the first half.