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Chelsea looked the better side in the second half as well but could not break down Real again and then had to withstand some late pressure from the hosts, who visit Stamford Bridge in the second leg on May 5.
The result ended City's six-game winning streak in all competitions as they remained on 74 points, 14 clear of second-placed Manchester United at the top of the standings having played two more games.
Goncalves scored in the 15th and 21st minutes for Chennayin before Diego Mauricio struck a screamer in the 64h minute to give Odisha some hope.
The 16-year-old won all six races in the first round of Novice Cup at the JK Tyre-FMSCI National Racing Championship.
Goalkeeper Thibaut Courtois made a catastrophic error and record signing Eden Hazard suffered yet another injury as the defending champions suffered their third defeat in 10 matches.
Going into the new season, Odisha FC have overhauled their foreign contingent.
The result means both Argentina (7 points) and Paraguay (5) remain unbeaten after the first three of their 18-game quest to reach the finals in Qatar.
Karim Benzema put Madrid ahead with a scorching strike from outside the area but Valencia replied with Soler's penalties and a bizarre own goal from Raphael Varane, inflicting a second defeat on Madrid this season.
The win moves Leeds up to third on 10 points, albeit having played an extra game, two points behind Villa, while leaders Everton, who have 13 points, are at Southampton on Sunday.
A late goal from Joaquin Correa helped Argentina come from behind to beat Bolivia 2-1 and maintain their 100 per cent record in the South American World Cup qualifiers.