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The Dutchman, who wrapped up the title last month in Japan with four races to spare, was unchallenged as he led from pole position to chequered flag.
Max Verstappen led from pole position at the Autodromo Hermanos Rodriguez, taking the chequered flag 15.186 seconds clear of Mercedes's Lewis Hamilton.
The title, clinched with three races to spare, ended an eight-year streak by Mercedes who have yet to win a race this season.
The Dutchman won his fifth race in a row and 11th in the season.
The Red Bull driver has taken his Formula One world championship lead into triple figures.
The Dutchman finished 17.8 seconds ahead of his Mexican team mate Sergio Perez.
Lewis Hamilton finished second for Mercedes.
Verstappen finished second while seven-time world champion Lewis Hamilton was third.
The deal, announced at the British Grand Prix on Thursday and initially running until 2025, will see Boss branding on the F1 cars with immediate effect and the company providing team apparel from 2023.
Daruvala chalked up over 130 laps combined over the two days.