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The Pole should have put Napoli ahead minutes later when compatriot Piotr Zielinski's cross found him unmarked in the penalty area but he headed wide.
Arsenal took the lead in the 14th minute through Ramsey, who finished off a sweeping move down the right by calmly slotting the ball past Napoli goalkeeper Alex Meret.
Arsenal's hopes of a top-four finish in the Premier League were dented as Everton captain Phil Jagielka took advantage of an unexpected late recall to score the winner in a dominant 1-0 victory at Goodison Park.
Teenage striker Moise Kean struck again to give Juventus a late 2-1 win over AC Milan after their opponents had taken the lead and dominated most of the match on Saturday.
The 31-year-old made 75 appearances for Argentina, scoring 31 goals. His last appearance was in the 2-1 win over Nigeria in the 2018 World Cup.
Despite the result, Juventus remain 18 points clear of second-placed Napoli at the summit of the table.
Arsenal became only the second team in Europa League history to win a tie after losing the first leg 3-1.
The Alturas is worth buying a Benz which is three or four times costlier.
Inter Milan, the winners of three European Cup and UEFA Cup titles apiece, also strolled through with a 4-0 home win over Rapid Vienna which completed a 5-0 dismissal.
Visitors Chelsea desperately needed a response after back-to-back humiliating away losses, with last Sunday's 6-0 thrashing by Manchester City following a 4-0 reverse at Bournemouth.