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Sixth-seed Rune, who had beaten Ruud at the Italian Open last month, littered the court with 26 unforced errors in the first two sets.
The Serbian World number three has 22 Grand Slam titles.
Top-ranked Carlos Alcaraz was imperious against Denis Shapovalov in the night session, blasting past the Canadian 6-1, 6-4, 6-2 to book a meeting with Lorenzo Musetti.
Elena Rybakina also booked a third round spot with a 6-3, 6-3 victory over rising Czech teenager Linda Noskova.
World number two Medvedev was tipped as a surprise contender for the Paris title following his Rome triumph, but the Russian was blown away by Wild in gusty conditions on Court Philippe Chatrier and crashed to a 7-6(5) 6-7(6) 2-6 6-3 6-4 defeat.
The 36-year-old Spaniard has not recovered from a hip injury.
Milan recovered some of the spark they lacked in the first leg but Inter's Martinez put the tie to bed when he struck powerfully from close range in the 74th minute at the San Siro
Inter host Milan in the second leg at the same venue on Tuesday and the winners will face Real Madrid or Manchester City in the final.
Argentia named World Team of the year after their triumph at the 2022 World Cup in Qatar.
The result meant that Simon Grayson's men reached a third final of the 2022-23 season, having made the summit clash of both the Durand Cup and the Indian Super League.