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The Dutchman, who had struggled this season after joining from Liverpool, struck in the 21st minute and headed in another goal six minutes before halftime.
It was the 34th time that Messi scored at least two goals in a Champions League game, bringing the Argentina captain's total to 123 goals in the tournament.
The takeover, fronted by PCP Capital Partners' chief executive Amanda Staveley, ends an unhappy era at St James' Park and means Newcastle will be one of the world's richest clubs.
Timo Werner, Trevor Chalobah and Ben Chilwell scored for the Blues.
The Argentine forward, who joined PSG on a two-year contract after leaving Barcelona, found the top corner superbly in the second half to add to Idrissa Gueye's early first-half opener and put the capital club top of Group A on four points.
Nkunku became only the fourth player to score a Champions League treble and end up on the losing side.
Istanbul:Lionel Messi's new club Paris St Germain (PSG) will play Manchester City, managed by the Argentine's former Barcelona coach Pep Guardiola, after being drawn together in Champion's League Group A on Thursday. Messi joined Qatar-owned PSG, who will also face Bundesliga side RB Leipzig and
Besides these four, 14 others are named as accused in the case registered by the agency for various offences.
The offences include criminal conspiracy, kidnapping and fabrication of evidence in connection with the arrest and detention of scientist Nambi Narayanan in the 1994 case.
The Former chief of Kerala Police has pointed fingers at ex-joint director of the IB.