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Italy set up a semifinal clash against Spain after first half goals from Nicolo Barella and Lorenzo Insigne led them to a 2-1 win.
The availability of both players has Belgium on tenterhooks ahead of the match in Munich on Friday after they were forced off the pitch injured in the last-16 clash with Portugal on Sunday.
Romelu Lukaku will likely be the main attacking threat when Belgium takes on Italy in Munich on Friday in the Euro 2020 quarterfinals. The Inter Milan forward has scored three goals in his team's four victories so far.
American Frances Tiafoe caused the first big upset by beating third seed Stefanos Tsitsipas 6-4, 6-4, 6-3.
Hazard found enough space after a swift passing move to rifle home from 20 metres and score against the run of play in the 42nd minute, setting up a quarterfinal clash with Italy.
Italy's squad depth proved decisive in the end as Juventus winger Chiesa and Atalanta midfielder Pessina spared their blushes with superb finishes.
Nestor Pitana, the Argentine who refereed the 2018 World Cup final, waved play on when the ball bounced off him outside Colombia's box and Brazil continued passing for Roberto Firmino to head in an equaliser.
Brazil had won their previous nine games coming into the match in Rio de Janeiro, all bar one of them without conceding a goal.
Belgium, who became the third team after Italy and the Netherlands to win all three group games, will face one of the third-placed sides in the round of 16 on Sunday.
Austria beat Ukraine 1-0 in their final Group C match to finish second and set up a last-16 clash with Italy.