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It was the Dutch driver's seventh win of a dominant campaign accelerating him ever closer to a third Formula One crown.
The 60-year-old coached Messi and Busquets at Barcelona in 2013-14 before managing Argentina from 2014-16.
The 32-year-old has a contract until June 2025 with an option for a further year, while the Spanish champions also said they had included a buyout clause of 400 million euros ($435.72 million).
Gundogan will leave City after captaining the English club to the Premier League, FA Cup and Champions League last season, ending a successful seven-year stint in England where he won 14 trophies, including five league titles.
The Dutch 25-year-old led every lap as he took his career tally to 41 wins, stepping up alongside Brazil's late triple champion Ayrton Senna in the record books.
Lewis Hamilton finished second while George Russell also made the podium in Barcelona.
The French champion lost to Clermont 3-2 in the final league game of the season.
Rico suffered 'a serious mishap due to a mule cart and a horse that hit him', his family said in a statement.
The win was Verstappen's fourth of the season, second in Monaco and 39th of his career.
Barcelona won 27th Laliga soccer title with 4-2 win over Espanyol