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Ousmane Dembele struck early and Lionel Messi converted a late penalty as Barcelona won 2-0 at Juventus after Alvaro Morata had three goals disallowed for offside for the Serie A side.
Lionel Messi became the first player to score in 16 consecutive Champions League seasons as he guided 10-man Barcelona to a 5-1 victory over Hungarian side Ferencvaros.
Barcelona fell to their first defeat in La Liga under new coach Ronald Koeman as they lost 1-0 at Getafe, hours after champions Real Madrid slipped to a 1-0 defeat at home to promoted Cadiz.
Philippe Coutinho scored his first league goal since returning to Barcelona to help his side draw 1-1 at home to an excellent Sevilla side in La Liga on Sunday.
Barcelona and Juventus were drawn together on Thursday in the Champions League group stage.
Bayern had not lost since December 7, 2019, and had gone 21 consecutive Bundesliga matches without defeat, winning their last 15.
Real Madrid scraped through 3-2 in an eventful game for their first win of the season.
Bayern Munich beat Sevilla 2-1 after extra time in the first European game played with fans in the stands since the sport returned amid the COVID-19 pandemic.
The former Barcelona player, 32, was an integral part of the Croatia side who reached the World Cup final in Russia before losing 4-2 to France.
His departure ends a trophy-laden six-year spell at Camp Nou during which Rakitic won four league titles, four Copa del Rey trophies plus the Champions League and Club World Cup.