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Nikola Mektic and Mate Pavic beat Novak Djokovic and Filip Krajinovic 7-5, 6-1 in a decisive doubles clash.
Kidambi Srikanth's fate hung in the balance after suffering a defeat in his second group match.
Serbia had their backs to the wall when Kazakh veteran Mikhail Kukushkin beat debutant Miomir Kecmanovic in a three-hour epic in the first singles rubber.
Sai Praneeth went down 12-21, 8-21 to Olympic champion and former world No.1 Viktor Axelsen of Denmark in the men's singles quarterfinals.
Axelsen ended the campaign of Srikanth, beating him 21-14, 21-18 in 37 minutes.
World champion Sindhu got the better of world No. 30 unseeded Turkish Neslihan Yigit 21-13, 21-10 in the quarterfinals.
Kerala's HS Prannoy defeated Malaysia's Liew Daren 22-20 21-19 in the opening round.
Playing her first tournament since winning the bronze medal at the Tokyo Olympics in August, Sindhu couldn't match her fifth seeded young Korean rival.
Sameer will lock horns with Tommy Sugiarto in the quarterfinals.
Sindhu won after a struggle against Busanan Ongbamrungphan 21-16, 12-21, 21-15 in 67 minutes in her last 16 match.