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Goalkeeper Thibaut Courtois made a catastrophic error and record signing Eden Hazard suffered yet another injury as the defending champions suffered their third defeat in 10 matches.
Maradona had the self-belief, determination and sheer arrogance to keep on making the defenders look like fools.
Severely depleted Real Madrid conceded a fourth penalty in two games as they drew 1-1 at Villarreal dropping points for the second game in a row.
This time around Kerala Blasters look solid and well-balanced, at least on paper.
Karim Benzema put Madrid ahead with a scorching strike from outside the area but Valencia replied with Soler's penalties and a bizarre own goal from Raphael Varane, inflicting a second defeat on Madrid this season.
The result left Real, winners of a record 13 titles in Europe's premier club competition, level on four points with Shakhtar Donetsk, one point behind leaders Borussia Moenchengladbach and two ahead of bottom placed Inter.
Eden Hazard scored his first goal for Real Madrid in over a year and Karim Benzema struck twice as the Spanish champions coasted to a 4-1 win at home to Huesca.
Goals by Karim Benzema and then Casemiro in the third minute of stoppage time rescued a 2-2 draw for the Spanish champions with Borussia Monchengladbach, who opened with a 3-2 loss at home to Shakhtar Donetsk last week.
Real Madrid captain Sergio Ramos once again proved to be the man for the big occasion as he converted a fiercely debated penalty to help his side to a 3-1 win.
Shakhtar Donetsk pulled off a shock 3-2 win away to 13-time winners Real Madrid in their Group B opener, despite the Ukrainian side missing 10 players due to injuries and COVID-19.