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Spain snatched a place in the Nations League final four after striker Alvaro Morata's late goal secured a 1-0 win over hosts Portugal on Tuesday.
A weekly podcast from Onmanorama, Extra Time brings together news, views and analysis from the world of football.
Veteran Ronaldo tucked away a 39th-minute penalty to claim his 699th club goal.
The result left United third in Group E, behind Real Sociedad and early leaders Sheriff Tiraspol, who beat Omonia Nicosia 3-0.
Manchester United won 3-1 at Old Trafford on Sunday.
Sancho provided a cool finish, rounding keeper Danny Ward and slipping the ball home in the 23rd minute after being set up by Marcus Rashford from a Bruno Fernandes break down the right.
Pep Guardiola's side bounced back from 0-2 to win 4-2 at the Etihad Stadium.
It was the first win for United's Dutch manager Erik ten Hag who was rewarded for his decision to leave Cristiano Ronaldo and club captain Harry Maguire on the bench.
Erik Ten Hag's United suffered a humiliating 0-4 defeat to Brentford.
The record seven-time winner is missing out for the first time since 2005.