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It was Pegula's 41st match victory in WTA main draws this year, with only world No. 1 Iga Swiatek (62) and the second-ranked Ons Jabeur (46) winning more.
The title, clinched with three races to spare, ended an eight-year streak by Mercedes who have yet to win a race this season.
She will join Iga Swiatek, Ons Jabeur, Jessica Pegula, Coco Gauff, Caroline Garcia, Aryna Sabalenka and Daria Kasatkina at the season finale.
Greek fourth seed Sakkari kept alive her hopes of making the Finals by surviving an early scare and fighting back from a set down to beat American Danielle Collins 5-7, 6-3, 6-3.
It will take weeks if not months to determine exactly how much of a role climate change may have played in this year's floods, but scientists agree it is supercharging extremes.
There is no doubt that the Indian American community will continue to get stronger. Any kind of hate has no place in this world, said Arun Agarwal, co-founder of the Indian American CEO Council.
The judges rewarded Nunes with a unanimous decision victory that saw her add the bantamweight belt to her featherweight title as she regained her status as reigning champion in two weight classes.
The suspect was described as a white man in overalls and a camouflage t-shirt.
Washington is the only actor or entertainment figure recognised this year, although sports figures Simone Biles and Megan Rapinoe are also among the medal winners.
It's among the deadliest tragedies to have claimed thousands of lives of people attempting to cross the U.S. border from Mexico in recent decades.