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Odisha suffered their second straight defeat and dropped a rung to fifth place with nine points from six matches.
The Scottish midfielder scored all three of his goals in the first half.
Odisha have nine points from four matches, three behind league leaders Mumbai City FC who have 12 points from five games.
Alvaro Vazquez put Blasters ahead in the 62nd minute, while Prasanth K doubled the lead in the 85th.
The world produces around 300 million tonnes of plastic waste every year, according to the United Nations Environment Programme.
Odisha join ATK Mohun Bagan at the top of the table with six points.
Odisha, who finished bottom last season, have started their campaign with an encouraging victory.
Xavi probably could not have asked for much more in his first game managing a struggling Barca team who are sixth in the standings, eight points behind leaders Sevilla.
After the presentation Xavi talked about how discipline will be a major factor in his project as Barcelona manager.
The La Liga club received the green light on Friday to sign the 41-year-old after they paid the release clause in his contract with Qatari side Al Sadd.