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The sixth-seeded duo got the better of John Peers GabrielaDabrowski 6-3, 3-6, 7-5.
Atalanta goalkeeper Juan Musso saved a penalty and a follow-up attempt but he couldn't keep out an own-goal by Davide Zappacosta from the resulting corner as Leipzig salvaged a 1-1 draw.
A sold-out Santiago Bernabeu stadium watched silently as a much-improved Barca under the command of new coach Xavi Hernandez dominated from the start.
Everton's plummet towards the relegation zone continued as they lost 1-0 at home to Wolverhampton Wanderers but Leeds United gained some respite with a last-gasp 2-1 win over bottom club Norwich City.
The match ended 1-1 with ATK Mohun Bagan star Roy Krishna being shown the red card.
Real Betis defeated 3-2 Zenit St Petersburg after scoring twice in the first 20 minutes.
The match ended 2-2 and dented their semifinal chances.
In the early stages of the match, Odisha FC applied a lot of pressure and was rewarded with a goal from Jonathas.
Romario scored in the 95th minute of the match.
Ivan Vukomanovic's Kerala beat Odisha FC 2-0 at the Tilak Maidan here on Wednesday.