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Xavi is set to replace caretaker coach Sergi Barjuan who was appointed after the club sacked Koeman.
Koeman was sacked after Barca's 1-0 loss to Rayo Vallecano on Wednesday, their fourth defeat in six games in all competitions.
Local media reports suggest that former midfielder Xavi Hernandez, who is currently in charge of Al Sadd in Qatar, and Belgium coach Roberto Martinez are the frontrunners for the role.
Goals from Karim Benzema and Kylian Mbappe earned them a 2-1 win over Spain at the San Siro.
A last-minute strike from Theo Hernandez secured the world champions a place in Sunday's final.
Griezmann struck in each half after his partnership with Karim Benzema bore fruit in satisfying fashion to put the world champions on 12 points from six matches at the top of the group.
The shooters came undone once again and the hockey team took a hammering.
The six-time world champion defeated Miguelina Hernandez Garcia of Dominican Republic, 4-1, on Sunday.
Boxer MC Mary Kom, badminton ace PV Sindhu, shooter Manu Bhaker and tennis star Sania Mirza will be in action on the third day of the Olympics on Sunday.
Peru, who reached the final of the last Copa America but had won just two of their 12 games since, got off to a good start in Goiania.