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Japan, who had also shocked Germany in their opener in Qatar, finished top of Group E to reach the last 16, a stage where they have faltered three times before.
Germany that won in 2014 have crashed out at the group stages in the two world cups since.
Spain finished second in Group E ahead of Germany on goal difference.
Spain edged Germany on goal difference to take the second spot.
The Spaniard Martinez managed Belgium for six years.
With 11 of their players in the squad over the age of 30, and a new World Cup cycle on the horizon, change is inevitable.
Croatia advance to the knockout stages finishing second in Group F.
The Atlas Lions clinched a spot in the last 16 of the World Cup for the first time since 1986.
Canada netted its first goal at the World Cup when Alphonso Davies rose highest in the penalty area to meet a lovely cross by Tajon Buchanan and powered the ball into the back of the net in the very 1st minute.
Canadian coach John Herdman has said his side is prepared for the big test.