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Harry Kane scored in a 3-0 round-of-16 victory for England against Senegal.
Giroud became France's all-time top scorer and Mbappe struck a a brace for the holders.
Olivier Giroud had put France ahead in the first half. Robert Lewandowski managed a late consolation for Poland.
Argentina will meet the Netherlands in the quarterfinals.
Group A toppers the Netherlands meet USA in the first round of 16 match.
'I am responsible for this disappointment. It is a great sadness and I assume all the responsibility of this huge failure,' said Martino, whose contract was reportedly due to expire after Mexico's World Cup campaign.
Australia, ranked 35 places below Argentina, have already surpassed expectations in winning twice to earn their place at Qatar's Ahmad bin Ali Stadium this weekend for one of the biggest games in their history.
Poland too progressed, with a better goal difference, after Mexico best Saudi Arabia 2-1.
Mexico finished with four points, level with Poland who lost 2-0 to group winners Argentina and had a superior goal difference of one to advance.
Argentina's victory moved the South American side to the top of the group and they will face Australia in the last-16 while second-placed Poland take on reigning champions France.