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Djokovic defeated Tsitsipas 6-0, 7-6 for his first title of 2022.
Madhavan, who directed the movie, plays the role of Indian scientist Nambi Narayanan in the film that has been shot simultaneously in multiple languages.
Rublev galloped to an early lead and barely gave his opponent a chance as he closed out the match with a powerful forehand winner for his first win over Djokovic and 11th career title.
Serbia international Kostic converted a fourth minute penalty and added another in the 67th with a low drive after Rafael Borre thundered in their second goal in the 36th for a 4-3 aggregate victory and a sensational win at the Camp Nou.
Four games will be played each day during the group-stage action that runs for 12 days.
William Hill installed Brazil, who rose to the top of the world rankings this week, as 5/1 favourites to win the tournament ahead of France (11/2), England (6/1), Spain (15/2) and Argentina (11/1).
The United States will face England, Iran and Europen play-off winners in Group B at the World Cup finals.
When FIFA and host nation Qatar stage the draw ceremony show on Friday, three of the 32 entries will be placeholders because the three-year qualifying programme was delayed and is still ongoing.
Bruno Fernandes scored a clinical double as Portugal beat stubborn visitors North Macedonia 2-0 to book their place in the finals.
Denmark lost 4-2 to the Netherlands in the international friendly, with Eriksen producing a stunning finish into the top corner in the 47th minute after he came on as a half-time substitute.