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Hummels and Mller made their returns for Germany two years after their last national-team appearances but had to settle for a 1-1 draw with Denmark.
Benzema, who has scored 29 goals in all competitions for Real this season, has not played for Les Bleus since 2015 after a blackmailing scandal over which he faces a trial in October.
The result was a body blow for Barca, who had lost just once in their previous 22 league games and no longer have the destiny of the title in their own hands.
The club’s recent lack of success, Messi's dissatisfaction with the management and many more factors seem to indicate that a departure from the club is on the cards.
The win took Barca back up to third place on 68 points, five behind leaders Atletico Madrid but with a game in hand.
Messi scored twice as Barcelona thrashed Athletic Bilbao 4-0 in the Copa del Rey final on Saturday to win the trophy for a record-extending 31st time with all the goals coming in the last half an hour.
Zinedine Zidane's side joined Atletico Madrid on 66 points and moved top of the table, although Atletico can reclaim first place when they visit Real Betis on Sunday.
The Catalans moved to within a point of Atletico Madrid at the top of La Liga.
Messi celebrated his record-equalling 767th appearance for Barcelona by scoring two goals in a 4-1 La Liga victory over Huesca.
Danish forward Martin Braithwaite grabbed the decisive goal with a scrappy diving header early in the extra period.