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Germany made a remarkable comeback to beat defending champions Belgium 5-4 in the sudden death shoot-out after playing a 3-3 in the regulation time.
The Argentine players kept their cool in the shootout after Kylian Mbappe had forced extra time and penalties with a hat-tick in a pulsating final.
Moroccos exit was tempered by their achievement of becoming the first African and Arab country to reach the World Cup semi-final, a feat widely celebrated.
France will play Morocco for a place in the final on Wednesday after the North Africans beat Portugal 1-0 in Saturday's earlier quarter-final.
Olivier Giroud had put France ahead in the first half. Robert Lewandowski managed a late consolation for Poland.
Australia defeated Denmark 1-0 and clinched second place in Group D.
Adrien Rabiot forced a save from Kasper Schmeichel for France.
Olivier Giroud netted twice to become France's joint record scorer as they fought back to put Australia to the sword.
Ballon D'Or winning striker Karim Benzema was ruled out of the tournament by a thigh injury.
Five-time champions Brazil always figure in the shortlist of teams likely to win the championship every time it is played.