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Messi responded to being benched by scoring twice as a substitute and leading Barcelona to a 5-2 home victory over Real Betis, snapping a four-game winless streak in La Liga for the Catalans.
Barcelona goalkeeper Neto made an embarrassing gaffe as his side was held to a 1-1 draw away to Alaves, despite playing the final half an hour with an extra man.
Ousmane Dembele struck early and Lionel Messi converted a late penalty as Barcelona won 2-0 at Juventus after Alvaro Morata had three goals disallowed for offside for the Serie A side.
Real Madrid captain Sergio Ramos once again proved to be the man for the big occasion as he converted a fiercely debated penalty to help his side to a 3-1 win.
Barcelona fell to their first defeat in La Liga under new coach Ronald Koeman as they lost 1-0 at Getafe, hours after champions Real Madrid slipped to a 1-0 defeat at home to promoted Cadiz.
Italy extended their unbeaten run to 19 games with a 1-1 draw at home to the Netherlands although they were knocked off the top of their Nations League group in the process.
The result kept holders Portugal top of League A Group 3 with seven points after three games, while France are second, also with seven. Croatia are third on three after winning 2-1 at home to Sweden, who are bottom with no points.
Olivier Giroud netted a double to take his international tally to 42 goals as the world champions crushed an injury and COVID-19-ravaged Ukraine 7-1 in a friendly.
Philippe Coutinho scored his first league goal since returning to Barcelona to help his side draw 1-1 at home to an excellent Sevilla side in La Liga on Sunday.
Barca's statement said Atletico will pay the Catalans six million euros in bonus payments to sign the 33-year-old.