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Jerry Mawihmingthanga scored Odisha FC's 99th ISL goal in the 78th minute to lift the Juggernauts up into second place.
Germany that won in 2014 have crashed out at the group stages in the two world cups since.
Spain finished second in Group E ahead of Germany on goal difference.
Spain edged Germany on goal difference to take the second spot.
Russia 2018 was the first time that Germany had failed to pass the group stage since 1938 - which was a different format.
Mesut Ozil has kept silent about Germany on the day of their fight for survival in the world cup.
Australia, ranked 35 places below Argentina, have already surpassed expectations in winning twice to earn their place at Qatar's Ahmad bin Ali Stadium this weekend for one of the biggest games in their history.
'I expect from Costa Rica a defensive performance as they did it against Japan. We have to find solutions against that,' said the German coach.
Stephanie Frappart, Neuza Back and Karen Diaz will become the first all-female refereeing team for a men's World Cup match.
Uruguay, third on one point, must beat Ghana in their final group game to have any chance of progressing.