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The Serb is just two wins away from a 21st major that would complete a calendar-year Grand Slam.
The world No. 1 next faces Italian Matteo Berrettini in a rematch of the Wimbledon final.
Novak Djokovic beat Italian Matteo Berrettini 6-7(4), 6-4, 6-4, 6-3 to win his sixth title at Wimbledon.
The Super Sunday begins with arch-rivals Brazil and Argentina locking horns at the Maracana Stadium to be crowned champions of South America.
Djokovic absorbed a barrage of powerful hitting from Canadian Denis Shapovalov to move on step closer to a record-equalling 20th Grand Slam title.
The 25-year-old took two hours and 36 minutes to get past the 14th-seeded Hurkacz.
All the cheers and standing ovations in the world could not save Federer from the Centre Court mauling as it seemed his 39-year-old body finally said enough is enough.
Italy's squad depth proved decisive in the end as Juventus winger Chiesa and Atalanta midfielder Pessina spared their blushes with superb finishes.
The Swiss, who beat Turkey 3-1, could still advance as one of the four best third-placed teams.
Djokovic repelled a stirring fightback by Italian Matteo Berrettini to claim a 6-3, 6-2, 6-7(5), 7-5 victory.