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The victory will act as a soothing balm for Rohit Sharma after the heartbreak in the World Cup final and the crushing defeat in the series opener.
The Navy veterans were on October 26 given death sentences by Qatar's Court of First Instance.
This was India's first Test win at Newlands and also ensured they shared a series in the Rainbow Nation for only the second time.
The plea claimed the allegations that the Adani Group, considered close to the Modi government, inflated its share prices.
Avesh Khan comes in as a replacement for the injured Mohammed Shami.
India were bowled out for 131 in the second innings after South Africa had posted 408.
Kohli and Iyer were invloved in a 68-run partnership for the fourth wicket.
South Africa is the only regular Test-playing country where India have yet to win a series.
The skipper wants his unit to be the first one to win a series in the Rainbow Nation in India's ninth attempt since 1992.
South Africa are justifiably proud of their unvanquished status against India at home and the Proteas can be expected to go all out to preserve this.