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Taylor Fritz blasted his way to a 6-3, 6-2 win over Australian Nick Kyrgios while Cameron Norrie fought back to beat former world No. 1 Andy Murray 3-6, 6,-3 6-4 in an all-British clash.
English champions City started their big close-season signing, Norway's Erling Haaland but, in contrast to Nunez, he had a disappointing debut, missing several chances and struggling to combine with his new team mates.
The three-day team event pits six of Europe's top players against six from the rest of the world.
The New Zealanders set a record by successfully chasing 20 off the 50th over.
His long-time friends and colleagues, including actor Al Pacino, remembered the actor as a 'daring' man who was very 'funny' and incredibly 'talented'.
He will next face unseeded Chilean Cristian Garin, who beat Kyrgios's compatriot Alex De Minaur to enter the last eight.
The hosts came close before losing by 4 runs against India.
Men's top seed and defending champion Novak Djokovic, chasing a 21st Grand Slam title after a troubled year, will open his campaign against South Korea's Kwon Soon-woo.
Liverpool were looking for their seventh European Cup triumph but despite their best efforts they were left in awe of Courtois's sublime performance.
Pep Guardiola's City bounced back from 0-2 to win 3-2 against Aston Villa.