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Philippe Coutinho scored a second half double and Everton added a cracking third as Brazil recovered from a sleepy start to beat Bolivia 3-0 in their Copa America opener.
Second-placed Venezuela will face the second team in Group B on Friday at the Maracana Stadium in Rio de Janeiro, while Peru must wait to see if their four points are enough to earn them a place as one of the two best third-placed sides.
Neymar limped off in the 17th minute after he appeared to twist his ankle and was carried to the dressing room with his right ankle wrapped in ice.
Brazil had three goals ruled out and missed a series of chances as they were held 0-0 by Group A rivals Venezuela on Tuesday.
Marta is also the only player, male or female, to have scored in five different World Cups.
Brazil's preparations for the Copa have been overshadowed by Neymar -- firstly the rape allegations against the striker, which he has denied, and then the ankle injury that ruled him out of the tournament last week.
The Selecao's golden boy is dominating the build-up to a tournament he will miss due to an ankle injury for all the wrong reasons.
Palmeiras fan Silvia Grecco talking to her blind son Nickollas during a derby match against Corinthians had been shown all over Brazil.
Lionel Messi returned from international suspension to score the winner.
Silvia Grecco and her son Nickollas, 12, have become minor celebrities for the Sao Paulo team Palmeiras after the mother was spotted on TV last year narrating one of their matches from the stands.
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