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London sides Tottenham Hotspur and Arsenal made winning starts as did fellow Premier League club Leicester City.
Gareth Bale's first appearance for Tottenham Hotspur for seven years, following his loan move from Real Madrid, was eclipsed by West Ham United who scored three times late on to draw 3-3 in the London derby.
Veteran striker Lior Refaelov's first-half goal gave Antwerp their second win in Group J and put them top with six points, three ahead of Spurs and LASK of Austria.
Tottenham Hotspur, Antwerp, Lille, Villarreal, Braga, Dinamo Zagreb, Red Star Belgrade, PSV Eindhoven, Granada, Bayer Leverkusen, Slavia Prague, Rangers and Benfica joined Milan in booking their places in the last 32 on the night.
Harry Kane scored his 250th career goal for club and country after laying on Son Heung-min's 10th league goal of the season as Tottenham beat Arsenal 2-0 to reach 24 points from 11 games.
United stretched their unbeaten run in all competitions to 12.
Bale has joined Spurs on a season-long loan deal and although the financial details of the move were not disclosed, British media reported that Tottenham will pay around 20 million pounds in wages and loan fees.
Everton ended a miserable run of form against Tottenham Hotspur as Dominic Calvert-Lewin's second-half header earned them a 1-0 away victory.
Spurs move on to 14 points from seven games and are just two behind leaders Liverpool but manager Jose Mourinho cautioned against talk of them being title contenders.
Liverpool are now unbeaten in 64 league games at Anfield setting a new club record and they were full value for the win.
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